Technologies of structural and functional materials

Starting from 2017, in order to popularize science and scientific achievements of Ukrainian scientists both in Ukraine and abroad, the National Academy of Sciences of Ukraine publishes the catalog "Advanced R&D Projects of the NAS of Ukraine" in eleven thematic areas

2022

Biocidal additive for marine paints with antifouling properties


Download page from catalog (2022)   


Purpose
Protective coatings for underwater metal structures and hydraulic engineering structures in fresh and seawater


Characteristics

Fine-dispersed refractory white powder, solubility in water — 0.015 g/100 ml, acute toxicity (LD50) relative to freshwater hydrobionts: Daphnia magna — 0.7 mg/l, Danio rerio (zebrafish) — 17 mg/l. The biocidal additive provides high resistance of the protective coating to biofouling at a mass fraction of 10%


Advantages

No analogues in Ukraine. Compared to traditional antifouling agents, it shows significantly lower ecotoxicity (more than one order of magnitude). Can be introduced into the composition of appropriate paint and varnish compositions as a fine-dispersed pigment


Development readiness level. Commercialization proposals 

IRL3, TRL3
Manufacture of a small batch on order. Searching for partners for mass production


Intellectual property protection

IRP3


Contact information

V.P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry of NAS of Ukraine

tel. +38 044 292 00 73, +38 098 451 75 69, e-mail: sergey.rogalsky@gmail.com

Rogalsky Serhiy P.
Candidates of sciences (PhD, chemistry)

Butyl oleate based on domestic raw materials


Download the page from the catalog (2022)  


Purpose
Plasticizer and substance for increasing the water resistance of materials in basic organic synthesis in the production process of rubbers and polymer materials; solvent in the paint and varnish industry; lubricating material in the textile industry, etc.


Characteristics
Homogeneous transparent liquid, colorless or yellow, with a kinematic viscosity in the range of 3.5—6.5 mm2/s, acid number not more than 0.50 mg KOH/g, and improved antioxidant stability


Advantages
Unlike known analogues, it has a lower cost, the product manufacturing process excludes the formation of acidic waste, which increases the environmental friendliness of production


Development readiness level
IRL4, TRL4
Manufacturing of small batches on order. Searching for partners to organize mass production


Intellectual property protection

IPR3


Contact information
V.P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry of NAS of Ukraine

+38 044 292 30 84, +38 050 182 58 86, e-mail: s.o.zubenko@ukr.net

Zubenko Stepan O.
Candidates of sciences (PhD, chemistry)

Fireproof coating for steel building structures


Download page from catalog (2022)


Purpose

In the construction industry, to increase the fire resistance limits of steel structures and ensure regulated fire safety of construction facilities


Characteristics

Fire resistance limit within R 30—120 minutes for metal structures with a cross-section coefficient of 250—90 m–1, if the coating thickness is 4—5 mm. Service life — at least 15 years under operating conditions of type Y (ETAG-018) indoors or in semi-enclosed spaces protected from atmospheric precipitation; biocidal resistance and minimal harmful impact on the environment ensured due to the balance of toxicity — biodegradability


Advantages

Reduction of negative impact on humans and the environment due to coating decomposition in fire conditions because of the absence of halogenated flame retardants and boric acid derivatives and reduction of smoke formation; reduction of fire protection treatment cost on average by 25—30% due to low price of fire protection paint, prolonged service life, and application technology. There are no analogs in Ukraine at the fire protection efficiency level (120 minutes)


Development readiness level
IRL5, TRL4
Searching for partners to organize mass production and implementation of the finished product


Intellectual property protection

IPR3


Contact information
L.M. Lytvynenko Institute of Physical-Organic Chemistry and Coal Chemistry of the NAS of Ukraine

tel. +38 067 176 31 08, e-mail: kachalova@nas.gov.ua

Kachalova Nataliya Mikhailovna
Candidates of sciences (PhD, physics & mathematics)

Hybrid technology for manufacturing flat thin-walled bimetallic and three-layer products


Download page from catalog (2022)


Purpose

Extension of the service life of machine parts operating in extreme conditions in mining, metallurgical, aviation, energy, and other industries by obtaining new wear-resistant bimetallic and three-layer products


Characteristics

The technology is based on the use of preliminary induction heating of a solid substrate under an oxygen-impermeable coating layer before pouring molten wear-resistant cast iron to ensure the formation of a reliable transitional diffusion zone between different metals. The technology allows manufacturing products weighing from 0.3 to 10 kg


Advantages
Expands capabilities: obtaining bimetallic and three-layer products for critical applications with enhanced physical and mechanical properties and a 2–3 times increased service life under intensive abrasive and impact-abrasive wear conditions, manufacturing bimetallic products with a steel substrate thickness of 3–5 mm


Development readiness level. Commercialization proposals
IRL6, TRL6
Searching for partners to implement the technology. Manufacturing small batches of castings to order


Intellectual property protection
IPR3


Contact information

Physical-Technology Institute of Metals and Alloys of NAS of Ukraine

tel. +38 044 424 12 50, e-mail: expo@ptima.kiev.ua

Candidates of sciences (PhD, engineering sciences)

Two-dimensional (2D) materials with different electronic properties for energy storage and conversion devices


Download page from catalog (2022)


Purpose

Materials for use in next-generation energy storage and conversion devices: conductors (graphenes with various degrees of heteroatom doping), semiconductors (transition metal dichalcogenides, carbon nitride, etc.), dielectrics (graphene oxide, boron nitride, etc.)


Characteristics
2D materials — doped graphenes and graphene oxide, metal dichalcogenides, carbon and boron nitrides, etc., with lateral nanoparticle sizes of 50–2000 nm, thickness of 1–10 molecular or atomic layers. Heteroatom content in doped graphenes up to 10%. Particles dispersed in organic solvent or water at concentrations of 0.05–3 mg/ml


Advantages
The simplicity and versatility of the original mechanochemical production method allow for fast and inexpensive fabrication of 2D materials based on various substances, which in their physical characteristics are not inferior to known analogues


Development readiness level. Commercialization proposals
IRL3, TRL3
Production of a small batch of 2D material selected by the customer. Searching for partners to test the suitability of 2D materials for use in energy storage and conversion devices on an industrial scale


Intellectual property protection

IPR2, IPR3


Contact information
L.V. Pisarzhevsky Institute of Physical Chemistry of the NAS of Ukraine

tel. +38 044 525 66 70, e-mail: s.v.kolotilov@gmail.com

Kolotilov Sergey Vladimirovich
Corresponding Member of the NAS of Ukraine

Electron-beam technologies for alloy preparation and casting production from them


Download the page from the catalog (2022) 


Purpose

Obtaining high-purity castings from refractory and highly reactive alloys for machine and shipbuilding, aerospace technology, energy industry, and medicine, as well as complex-alloyed alloys, cast composites, and special alloys for a wide range of alloys


Characteristics
Vacuum technology for remelting and refining metals and alloys using a concentrated electron beam with electromagnetic stirring of the melt. Capability to produce castings weighing 0.5—20 kg


Advantages
Remelting of highly reactive and refractory metals and alloys, including titanium and zirconium. Obtaining finished cast products and semi-finished products from titanium and its alloys with mechanical properties at the level of deformed metal. Ability to use up to 100% of waste in the casting production process


Development readiness level. Commercialization proposals
IRL6, TRL8
Searching for partners to implement the technology. Production of small batches of castings on order


Intellectual property protection

IPR1, IPR2, IPR3


Contact information
Physical-Technology Institute of Metals and Alloys of NAS of Ukraine

tel. +38 044 424 12 50, e-mail: expo@ptima.kiev.ua

Candidates of sciences (PhD, engineering sciences)

Welding materials for complex-alloy bronzes


Download the page from the catalog (2022) 


Purpose

Welding, sealing casting defects, surfacing on steel of complex-alloyed bronzes


Characteristics
Chemical composition of the deposited metal developed by welding materials

Aluminum bronzes:

Type of welding materialChemical composition of deposited metal (average values), %Welding method
AlMnNiFeCu
Flux-cored wire7.50.560.752.1BalanceMIG, SAW
8.50.70.82.2
9.90.851.23.0
8.9
10.71.52.6
Composite flux-cored wire8.21.12.02.8
6.59.81.82.5
Covered electrodes≥7.52.01.0-MMA


Tin bronzes:

Type of welding materialChemical composition of deposited metal (average values), %Welding method
Sn
PMn
Cu
Flux-cored wire9.5—10.5
0.4—0.5
-BalanceTIG, SAW
Covered electrodesANBO-16.0—8.0
0.2—0.5
0.6—0.9
MMA
ANBO-29.0—11.0
0.5—0.8
0.5—0.8


Advantages
Improvement of mechanical and antifriction properties compared to cast bronzes of the same chemical composition. Saving of scarce non-ferrous metals


Development readiness level. Commercialization proposals
IRL6, TRL6
Manufacture and supply of welding materials on order


Intellectual property protection

IPR1, IRP3


Contact information
Paton Electric Welding Institute of NAS of Ukraine

tel. +38 096 194 34 33, e-mail: pwi_37@ukr.net

Maidanchuk Taras Borysovych
Candidates of sciences (PhD, engineering sciences)

Impregnated fibrous chemosorbent of acidic gases with "Activation" indication of the absorption capacity "ECOFIL-1(I)"


Download the page from the catalog (2022) 


Purpose

For the production of sorption-filtration fibrous materials, from which gas mask elements (GME) are made for gas cleaning equipment, in particular respirators for protection against toxic acidic gases (SO2, SO3, SiF4, HF, HCl, and Cl2) and vapors


Characteristics
The moment of "activation" of the dynamic absorption capacity of the GME during the absorption of acidic gases and vapors is visually determined in a timely manner, which allows for the regulation of GME usage. The socio-economic effect is ensured by the prevention of occupational diseases and savings on chemosorption material, as well as by reducing the number of personnel monitoring the effectiveness of respirators


Advantages

Visual indication of the "activation" moment of the dynamic absorption capacity of "Ekofil-1(I)" allows for timely replacement of expensive GME respirators without using additional devices and ensures their further use


Development readiness level. Commercialization proposals
IRL8, TRL7
Production of small batches on order. Searching for partners to update equipment fleet, organize advertising, and mass production


Intellectual property protection

IPR1, IRP3


Contact information
Physico-Chemical Institute for Environmental and Human Protection of the Ministry of Education and Science of Ukraine and the National Academy of Sciences of Ukraine

tel. +38 096 499 36 88, e-mail: eksvar@ukr.net


Contact person

Ruslan Yevheniyovych Khoma

Impregnated fibrous chemosorbent of main gases with "Activation" indication of absorption capacity "ECOFIL-2(I)"


Download the page from the catalog (2022) 


Purpose

For the production of sorption-filtration fibrous materials, from which gas mask elements (GME) are made for gas purification equipment, in particular respirators for protection against toxic main gases (NH3, organic amines) and vapors


Characteristics
The moment of "activation" of the dynamic absorption capacity of the GME during the absorption of main gases and vapors is visually determined in a timely manner, which makes it possible to regulate the use of GME. The socio-economic effect is ensured by the prevention of occupational diseases and the saving of chemosorption material, as well as by reducing the number of personnel who monitor the effectiveness of respirators


Advantages
The dynamic absorption capacity of "Ekofil-2(I)" allows timely replacement of expensive GME respirators without the use of additional devices and ensures their further use


Development readiness level. Commercialization proposals
IRL8, TRL7
Manufacturing of small batches on order. Searching for partners to update equipment fleet, organize advertising, and mass production


Intellectual property protection

IPR1, IPR3


Contact information

Physical and Chemical Institute for Environmental and Human Protection of the Ministry of Education and Science of Ukraine and the National Academy of Sciences of Ukraine

tel. +38 096 499 36 88, e-mail: eksvar@ukr.net


Contact person

Ruslan Yevheniyovych Khoma

Catalytic systems for converting biomass into high-value products


Download the page from the catalog (2022) 


Purpose

Chemical technologies for processing biomass into high value-added products, which are the basis (monomers) for creating new and replacing existing materials synthesized from petrochemical or coal chemical products


Characteristics

High catalytic activity at low temperatures for oxidation processes (up to 80 °C), which usually occur at 150–400 °C. Process selectivity, ensuring it with maximum compliance with the requirements of "green" chemistry


Advantages
Low cost and availability of catalytic system components; efficiency in oxidation processes where oxygen is the reagent – the cheapest "green" oxidant; possibility of modifying the components of the catalytic system depending on the initial conditions; high biodegradability of the created materials in natural conditions


Development readiness level. Commercialization proposals
IRL4, TRL3
Manufacturing a batch of catalyst on order, consultations on its use in the technological process. Development of oxidation process technology for biomass substrates using the catalytic system


Intellectual property protection

IPR2


Contact information
Institute of Physical Organic Chemistry and Coal Chemistry named after L.M. Lytvynenko NAS of Ukraine

tel. +38 067 176 31 08, e-mail: kachalova@nas.gov.ua

Kachalova Nataliya Mikhailovna
Candidates of sciences (PhD, physics & mathematics)

MHD plasma technology for obtaining reinforced aluminum alloys and cast products from them for high-tech engineering industries


Download the page from the catalog (2022) 


Purpose

Preparation and dosing in the foundry of molds and crystallizers of structural, composite, and functional aluminum alloys, obtaining cast products for critical applications


Characteristics
The technology is based on combined thermomechanical action on the liquid metal by plasma and electromagnetic fields. The principle is implemented in a foundry magnetodynamic installation with a capacity of up to 630 kg of aluminum melt with a total electrical power of up to 70 kW, equipped with a plasma torch with a power of up to 10 kW for deep treatment of alloys with high-temperature gas-reactive environments and immersed plasma


Advantages
The technology and equipment have no analogues in the world. They allow dispersing the structure and increasing the strength of the cast metal by 20–30%, and plasticity by 2–3 times with economical use of energy resources and materials


Development readiness level. Commercialization proposals
IRL5, TRL4
Manufacturing equipment to order and mastering the technology


Intellectual property protection

IPR1, IPR2, IPR3, IPR4


Contact information
Physical-Technology Institute of Metals and Alloys of NAS of Ukraine

tel. +38 044 424 12 50, e-mail: expo@ptima.kiev.ua

Candidates of sciences (PhD, engineering sciences)

Method of non-destructive depth-selective diagnostics of microdefects in the structure


Download page from catalog (2022) 


Purpose

Investigation of defects in the structure of single crystals for scientific instrument making, nanoindustry, microelectronics


Specifications
Sensitivity to defects (by concentration or volume fraction): 10–8—10–6
Samples — single crystal plates sized up to 50 × 50 × 5 mm


Advantages
Thanks to the transition from the traditional kinematic to the dynamic scattering picture, diagnostics without damaging the object is enabled: with an increase in sensitivity to structural imperfections by 4—6 orders of magnitude; with the ability to simultaneously determine many structural parameters; with the ability to diagnose fast processes; with significant simplification of methods


Development readiness level. Commercialization proposals
IRL3, TRL3
Conducting research on order. License sale to equipment manufacturers


Intellectual property protection

IPR3


Contact information
G.V. Kurdyumov Institute of Metal Physics of the NAS of Ukraine

tel. +38 095 280 81 37, e-mail: filatova@imp.kiev.ua

Candidates of sciences (PhD, physics & mathematics)

Monocrystals of paratellurite TeO2


Download the catalog page (2022) 


Purpose

Manufacture of working elements of acousto-optic devices, in particular modulators, light deflectors, delay lines


Specifications
High optical quality single crystals with a diameter up to 45 mm and a length up to 60 mm. Acousto-optic quality factor M2 = 1143.8 × 10–15s3/kg for isotropic interaction of linearly polarized optical waves with a transverse acoustic wave


Advantages

Unlike known analogs, they have the highest values of the acousto-optic quality factor in the visible spectral range


Development readiness level. Commercialization proposals
IRL6, TRL6
Manufacture of small batches of single crystals to order, manufacture of working elements from single crystals with specified parameters (dimensions, crystallographic orientation, and degree of mechanical processing)


Intellectual property protection

IPR1, IPR3


Contact information
Institute of Electronic Physics of NAS of Ukraine

tel. +38 050 884 80 18, e-mail: romanova.iep@gmail.com

Roman Ivan Yuriyovych
PhD in Chemistry