Publications on the project |
104 Polycyanurate/Carbon Nanotubes nanocomposites |
Authors: |
Alexander Fainleib, Liubov Bardash
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Summary: | In this paper the recent works concerning synthesis and characterization of Polycyanurate/Carbon Nanotubes nanocomposites are reviewed. In particular, the thermal, mechanical, spectral as well as morphological studies of functionalized or virgin Single-Walled or Multi-Walled Carbon Nanotubes-Polycyanurate Nanocomposites are discussed. | |
Keywords: | | |
Edition: | | | | 2010,
287-298,Ukrainian |
104 New IPNs for High-Tech applications: Synthesis and Functional Properties. |
Authors: | B. Youssef, A. Vuillequez, O. Grigoryeva, M. Benzhora, J. Grenet,
A. Fainleib, J.M. Saiter | |
Summary: | Resins based on cyanates and polymethacrylates, possessing interesting thermal, mechanical, fire-retardant and other functional properties, can be easily prepared. They can serve as ideal low-density matrices for composites, offering attractive properties for
advanced aeronautical applications. This work discusses various routes to prepare different interpenetrating polymer networks (IPNs) based on cyanate esters or isocyanurate urethane methacrylate networks: a hybrid network comprising flexible segments of polybutylene glycol adipate (PBGA), a semi-IPN containing flexible crystalline linear polyurethane (CPU) based on PBGA, a full IPN possessing flexible polyurethane methacrylate (PUMA) based on PBGA, and a full IPN linked with flexible silicone-based isocyanurate urethane methacrylate (ICUMA). We will comment on the above-mentioned systems and compare their thermomechanical, mechanical and fire-retardant properties. | |
Keywords: | Polycyanurate; polyurethane; methacrylate; silicone; hybrid network; semi-IPN; full IPN; grafted IPN; thermal stability | |
Edition: | Matériaux & Techniques | | | 2011,
297–304,English |
104 Thermostable polycyanurate-polyhedral oligomeric silsesquioxane hybrid networks: synthesis, dynamics and thermal behavior |
Authors: | Starostenko O., Bershtein V., Fainleib A., Egorova L., Grigoryeva O.,
Sinani A., Yakushev P.
| |
Summary: | A series of hybrid polycyanurate - epoxy cyclohexyl-functionalized polyhedral oligomeric silsesquioxane (PCN/ECH-POSS) nanocomposite networks with ECH-POSS content varying from 0.025 to 10 wt.%were synthesized and characterized using FTIR, DSC, DMA and CRS techniques. It was revealed that already as low as 0.025 wt. % POSS cardinally changed PCN glass transition characteristics including the strong shift of the transition onset to higher temperatures and manifesting a second, higher-temperature glass transition characterizing interfacial dynamics; additionally, enhancing creep resistance and thermal stability at the earlier stage of degradation were observed. | |
Keywords: | glass transition; nanocomposites; polycyanurates; POSS | |
Edition: | Macromol. Symp. | | | 2012,
90-96,English |
104 Thermosetting Cyanate Ester Resins Filled with CNTs |
Authors: | Fainleib A., Bardash L., Boiteux G., Grigoryeva O. | |
Summary: | In this Chapter, a review on synthesis, structure and properties of the novel nanocomposites based on high performance thermosetting polymer matrix, polycyanarate, from Cyanate Ester Resins and the nanofiller, Carbon Nanotubes, is given and the own results of the authors are discussed | |
Keywords: | | |
Edition: | Advances in prog. Thermoplastic and thermosetting polym., perspect. and appl. (Ye. Mamunya, and M. Iurzhenko, editors), Tehnopress editura, Iasi, Romania | | | 2012,
379-424,English |
104 Electric conductivity of the nanocomposites based on thermosetting polymers and carbon nanotubes |
Authors: | V.V. Korskanov, Y.P. Mamunya, L.V. Bardash, A.M. Fainleib | |
Summary: | The dependence of the electric conductivity of nanocomposites based on thermosetting polyepoxides and polycyanurate on the concentration of carbon nanotubes has been investigated. Low values of percolation threshold at a volume fraction of carbon nanotubes from 0.001 to 0.002 are observed for all the samples studied. The values of percolation threshold are in good agreement with the results of mathematical modeling. It is established that the electrical properties of the nanocomposites based on thermosetting polymers studied can be characterized in the frame of a general theoretical model despite a difference in the properties of two polymer matrices. | |
Keywords: | | |
Edition: | Reports of the National Academy of Sciences of Ukraine | | | 2012,
112-118,Russian |
104 104 Hybrid organic-inorganic thermostable nanomaterials suitable for operation in extreme conditions |
Authors: | Grigoryeva O.P., Fainleib A.M., Bardash L.V., Starostenko O.M., Gusakova K.G., Danylenko I.Yu. | |
Summary: | | |
Keywords: | | |
Edition: | | | | 2014,
693-698,Russian |
104 Structure and properties of novel thermostable polycyanurate/polybutylene terephthalate semi-IPNs and nanocomposites obtained in situ |
Authors: | Grygoryeva O.P., Fainleib A.M., Bardash L.V., Boiteux G. | |
Summary: | | |
Keywords: | | |
Edition: | | | | 2013,
361-363,Ukrainian |
104 Structure and properties of nanocomposites based on polybutylene terephthalate synthesized from cyclic butylene terephthalate oligomers in situ with MWCNTs |
Authors: | Fainleib A.M., Bardash L.V., GRigoryeva O.P., Boiteux G. | |
Summary: | | |
Keywords: | | |
Edition: | | | | 2013,
364-366,Ukrainian |
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The events in the framework of the project |
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104 6. Nanochemistry Purpose: Expected results:Release of new product: technology Stage 1: Stage 2: Stage 3: Stage 4: Stage 5:
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