Publications on the project |
101 Phosphorylated Azolylidenes: Novel Ligands for Dinuclear Complexes of Coinage Metals |
Authors: | A. Marchenko, H. N. Koidan, A.N.Hurieva,O.V.Gutov,A.N.Kostyuk, C.Tubaro,S. Lollo,A.Lanza,F.Nestola, A. Biffis | |
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101 101 101 101 101
The events in the framework of the project |
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101 6. Nanochemistry Purpose:Synthesis, investigation of structute and properties of novel asymmetric catalysts based on chiral nano-sized calixarenes and diphosphine ligands featuring spacially organized metal-coordinatng groups Expected results:Issue of new types of products: methods, theories Stage 1:Design and synthesis of chiral molecular blocks for formation of nano-sized systems Stage 2:Chemical modification of synthesized molecular structures in order to achive nano-sized parameters Stage 3:Synthesis of ligands for metal-complex catalysts of asymmetric synthesis Stage 4:Preparation organometallic and organocatalytic systems for asymmetric catalysts Stage 5:Development of methods for attaching the catalysts on polymer or inorganic nano-sized support for use in asymmetric processes
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